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A compound `Co(en)_2xx(NO_2)_2Cl` exists different isomeric forms (i.e., A, B and C) with the characteristic properties as given below :
`Co(en)_2xx(NO_2)_2Cl`
Property | A | B | C | |
(i) | Optical activity | `xx` | `xx` | ✓ |
(ii) | Re action with `AgNO_3` | `xx` | ✓ | ✓ |
(iii) | Reaction with en | `xx` | `xx` | ✓ |
A. |
|
B. |
|
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C. |
|
D. |
None of these |
B is optically inactive, so it is also a trans isomer. As it reacts with `AgNO_3` so Cl-atom is ionisable and is out side the sphere. It does not react with en so the two `NO_2` groups are most adjacent