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The reaction ; `2O_3 -> 3O_2`, is assigned the followig mechanism :
(I) `O_3` ⇌ `O_2+O`
(II) `O_3 +O overset{mbox{(slow)}}{rightarrow} 2O_2` The rate law of the reaction will therefore be
A. |
`r alpha [O_3]^2[O_2]` |
B. |
`r alpha [O_3]^2[O_2]^-1` |
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C. |
`r alpha [O_3]` |
D. |
`r alpha [O_3][O_2]^-2` |
Step II, being r.d.s. Rate of overall reaction = Rate of Step II
= `K_(II)[O_3 ][O]` Putting the value of [O] from the equilibrium of step I, we get