Failed to connect to MySQL: Access denied for user 'examnext_online'@'localhost' (using password: YES) Consider the following acids `o–CH_3OC_6H_4COOH;``o–HOC_6H_4COOH ``C_6H_5COOH`Arrange the acids in the decreasing order of their acidity - Sarthaks eConnect
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Practice Online Test Series for JEE Main 2018 & NEET 2018

Consider the following acids :

  1. `o–CH_3OC_6H_4COOH;`
  2. `o–HOC_6H_4COOH `
  3. `C_6H_5COOH`

Arrange the acids in the decreasing order of their acidity :

A.

2 > 1 > 3

B.

2 > 3 > 1

C.

1 > 2 > 3

D.

3 > 1 > 2

Solution

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Best answer

Both ortho-subtituted acids are stronger than benzoic acid due to ortho effect. Salicylic acid is strongest because of intermolecular H-bonding.