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Which of the following shows correct Lewis acidic strength order of trihalides of boron ?

A.

`BCl_3 > BBr_3 > BF_3 > Bl_3`

B.

`BF_3 < BBr_3 < BCl_3 < Bl_3`

C.

`BF_3 < BCl_3 < BBr_3 < Bl_3`

D.

`BF_3 > BCl_3 > BBr_3 > Bl_3`

Solution

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Best answer

This cannot be explained on the basis of electronegativity of substituent attached actually. This can be explained on te basis of `p_(pi)-p_(pi)` back bonding, greater the `p_(pi)-p_(pi)` back bonding lower is its lewis acidic strength.


`rarr`  Back bonding tendency decreases

`rarr`  Lewis acidity increases